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SH-9608/A有机硅树脂乳液

本品是一种非离子的甲基苯基有机硅树脂乳液,广泛应用于耐热性工业涂料,具有耐高温性能和成膜性与气干性能。

所属分类:

硅树脂


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产品描述

SH-9608/A有机硅树脂乳液

  • 性能及用途

本产品是一种非离子型甲基苯基有机硅树脂乳液,广泛应用于耐热性工业涂料,具有优良的耐高温性能、成膜性与气干性能,可单独或复配作为耐热性罩光清漆使用,其清漆可达350℃,色漆可达650~700℃,可以用水稀释,符合环保法规要求,并且与有机树脂具有良好的相容性,可以复配有机树脂(如丙烯酸、聚酯、环氧等)使用,实现有机树脂的高装饰性和硅树脂的耐热性的兼具效果。

  • 主要技术指标

项  目

指  标

外  观

乳白色液体

粘度(25℃)/s

13-30

固含量(120℃,2h)/%

50±2

  • 推荐应用

1、广泛的工业耐热应用,如锅炉、热源管道、电热器和燃炉等;

2、广泛适用于烤炉、烤箱等耐热炊具设备。

  • 包装及贮运

一般为200kg、50kg塑料桶包装;在5~-36℃、阴凉干燥环境下密封贮存,贮存期6个月,超期检验合格仍可使用。

  • 施工参考

建议制备水性无树脂色浆,再配合树脂乳液一起使用;树脂乳液具有较好的室温自干性,能赋予工件初期的保护性和可搬运性能;但是如果想要获得更加优良的耐热性能和物理机械性能, 建议200-280℃ 15-60min条件下完全固化,优选250℃ 30min 或者 280℃ 15min。

  • 推荐应用配方

对于水性树脂9607、9608/A,均可参考如下表所示的推荐配方作为起始配方,以制备单组份烘烤型色漆:

编号

组份

质量占比/%

备注

1

去离子水

8.0

 

2

成膜助剂

1.5

如二丙二醇甲醚或乙二醇丁醚

3

基材润湿剂

0.3

如空气化学 104E

4

多聚磷酸钠分散剂水溶液,20%有效分

1.2

如 POLYRON® N,澳汉盛川化工

5

水性分散剂

2.8

如 BYK 190

6

水性消泡剂

0.1

如BYK 024,Tego 901,etc.

7

滑石粉

2.4

如辽宁海城鑫达滑石粉

8

云母粉

3.2

如滁州格瑞矿业

9

铜铬黑,铁锰黑

19.2

如美国福禄PK 3095

或德国朗盛拜耳乐303T

10

有机树脂硅乳液

60

湖北隆胜四海

11

增稠剂

1.0

如美国OMG 0625

或海明斯膨润土DE

12

流平剂

0.3

如BYK 381

  1. 低速剪切混合组分1-6;
  2. 依次加入组分7-9,低速剪切混合,高速研磨(如线速度7.0 m/s砂磨);
  3. 低速剪切下,逐步加入有机硅树脂乳液,并依次加入增稠剂调整至适合施工粘度;流平剂根据需要添加;
  4. 不建议直接以该有机硅树脂乳液研磨色浆;如需要混合其它有机树脂一起使用,可根据实际情况以有机树脂进行色浆研磨,再混拼入有机硅树脂乳液;使用前有必要对相容性进行测试,pH值是否匹配,该有机硅树脂乳液一般呈现接近中性,可以根据需要以5%氢氧化钾溶液或5%醋酸溶液调整pH值。
  5. 推荐干燥条件及特性:室温表干≥45min,230℃ 1.0h 或 250℃ 30min 或 280℃ 15min。

SH-9608/A Silicone Resin Emulsion

Ⅰ. Features

This product is a non-ionic, methyl phenyl silicone resin emulsion designed for heat-resistant industrial coatings. It offers excellent high-temperature resistance, film-forming properties, and air-drying performance, and can be used alone or in combination as a heat-resistant overprint varnish. The varnishes can withstand temperatures up to 350℃ while paints 650℃~700℃. It is infinitely dilutable with water and complies with environmental regulations. Additionally, it shows great compatibility with organic resins and can be used together with them (such as acrylic, polyether, epoxy, etc.), achieving a balance between the high decorative properties of organic resins and heat resistance of silicone resin.

Ⅱ. Technical Data

Item

Index

Appearance

Milky white liquid

Viscosity (25℃, s)

13~30

Solid Content (120℃, 2h, %)

50±2

Ⅲ. Applications

  1. Widely used in industrial heat-resistant applications, such as boilers, heat supply pipelines, electric heaters, furnaces, etc.
  2. Widely used in heat-resistance cookware equipment such as roasters and ovens.

Ⅳ. Packaging and Storage

Standard packaging is 200kg or 50kg plastic drum. The shelf life of this product is 6 months when stored in a cool and dry environment at 5℃~36℃ in unopened packaging. Re-test the product according to the specifications after expiry. It may remain usable if it still meets the requirements.

Ⅴ. How to Use

It is suggested to prepare a waterborne resin-free color paste, and then use it together with this resin emulsion. This product has good room-temperature self-drying properties, providing the workpiece with initial protection and handling ability. However, to achieve superior heat resistance and physical-mechanical properties, it is recommended to fully cure at 200℃~280℃ for 15~60 minutes, preferably at 250℃ for 30 minutes or at 280℃ for 15 minutes.

Ⅵ. Recommended Formulations

For water-based resins such as 9607 and 9608/A, the recommended formulation shown in the table below can be used as a starting point to prepare single-component baking paints.

No.

Component

Wt%

Remarks

1

Deionized water

8.0

 

2

Coalescing agent

1.5

e.g.dipropylene glycol methyl ether (DPM) or ethylene glycol butyl ether (EB)

3

Substrate wetting agent

0.3

e.g. Evonik (Surfynol 104E)

4

Sodium polyphosphate dispersant aqueous solution, 20% active content

1.2

e.g. ASCC (POLYRON® N)

5

Waterborne dispersant

2.8

e.g. BYK 190

6

Waterborne defoamer

0.1

e.g. BYK 024, Tego 901, etc.

7

Talc powder

2.4

e.g. Xinda Talc (Talc powder)

8

Mica powder

3.2

e.g. Anhui Grea New Material Technology

9

Copper chromite black, iron manganese black

19.2

e.g. Flow Int’l (PK 3095),

LANXESS (Bayferrox 303T)

10

Silicone resin emulsion

60

e.g. Hubei Longsheng Sihai

11

Thickener

1.0

e.g. OMG 0625,

or Elementis (BENTONE DE)

12

Leveling agent

0.3

e.g. BYK 381

  1. Mix components of no. 1~6 under low-speed shear.
  2. Add components of no.7~9 sequentially, mix under low-speed shear, and then grind at high speed (e.g., bead milling with a tip speed of 7.0 m/s).
  3. Under low-speed shear, gradually add the silicone resin emulsion, and then add thickener  sequentially and adjust to an appropriate application viscosity. Add leveling agent as needed.
  4. It is not suggested to grind the color paste directly with this silicone resin emulsion. Therefore, if this product is used in combination with other organic resins, grind the color paste with organic resins first based on actual conditions, and then blend the mixture with this silicone resin emulsion. It is noted that a compatibility test of the two is needed before use, particularly on whether their pH values match. Generally, pH of this silicone resin emulsion is around 7 and can be adjusted as needed with a 5% potassium hydroxide solution or a 5% acetic acid solution.
  5. Recommended drying condition: surface dry at room temperature for over 45 minutes and fully cure at 230℃ for 1 hour, or 250℃ for 30 minutes, or 280℃ for 15 minutes.

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